Production
Silica aerogel is made by drying a hydrogel composed of colloidal silica in an extreme environment. Specifically, the process starts with a liquid alcohol like ethanol which is mixed with a silicon alkoxide precursor to form a silicon dioxide sol gel (silica gel). Then, through a process called supercritical drying, the alcohol is removed from the gel. This is typically done by exchanging the ethanol for liquid acetone, allowing a better miscibility gradient, and then onto liquid carbon dioxide and then bringing the carbon dioxide above its critical point. A variant on this process involves the direct injection of supercritical carbon dioxide into the pressure vessel containing the aerogel. The end result removes all liquid from the gel and replaces it with gas, without allowing the gel structure to collapse or lose volume.
Aerogel composites have been made using a variety of continuous and discontinuous reinforcements. The high aspect ratio of fibers such as fiberglass have been used to reinforce aerogel composites with significantly improved mechanical properties.
Resorcinol-formaldehyde aerogel (RF aerogel) is made in a way similar to production of silica aerogel.
Carbon aerogel is made from a resorcinol-formaldehyde aerogel by its pyrolysis in inert gas atmosphere, leaving a matrix of carbon. It is commercially available as solid shapes, powders, or composite paper.