搜索 - 科创

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Kolbe 电解是是一类有机电化学反应，羧酸 R-COO- 在阳极上氧化脱羧后生成自由基 R·，而后两个自由基结合生成二聚体 R-R。

又搜了一些论文，发现 Kolbe 电解对铂电极有腐蚀，实用性可能是个问题，而 BDD 电极对 Kolbe 产物的选择性较差。不过研究的都是电解乙酸，不知道电解富马酸是什么情况。

我感觉很可能会像kolbe电解一样出一堆偶氮化合物，二亚胺化合物，烷烃化合物。产率可以想到很低。电化学其实副反应比你想的多的多。

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