搜索 - 科创

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待日后各条件允许后继续该课题的研究鉴于该系列的化合物在业余届属于首次合成，具有一定的新颖性，近日也有坛友建议发表相关文章，笔者在此总结并发表部分$$1$$标题化合物的制备步骤，希望对有意图合成该系列化合物的爱好者有所帮助五氮唑的合成意义在论坛前人之述备矣

三、五氮唑阴离子盐的能量及密度 3.1 五氮唑羟胺盐 △Hf(NH3OH+，g)=686.07 kJ/mol △Hf(N5-，g)=229.49 kJ/mol △HL=602.57 kJ/mol △Hf

如图1所示，本文作者利用取代苯胺的盐酸盐和亚硝酸钠反应形成重氮化合物，接着和叠氮化钠发生环加成反应，m-CPBA氧化条件下切断C-N键得到五氮唑的钠盐化合物2, 得到了稳定的白色固体粉末NaN5水合物，

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